Date of Award:
Master of Science (MS)
This study measures Radiation Induced Conductivity (RIC) in five insulating polymeric materials over temperatures ranging from ~110 K to ~350 K: polyimide (PI or Kapton HNTM and Kapton ETM), polytetraflouroethylene (PTFE or TeflonTM), ethylene-tetraflouroethylene (ETFE or TefzelTM), and Low Density Polyethylene (LDPE). RIC occurs when incident ionizing radiation deposits energy and excites electrons into the conduction band of insulators. Conductivity was measured when a voltage was applied across vacuum-baked, thin film polymer samples in a parallel plate geometry. RIC was calculated as the difference in sample conductivity under no incident radiation and under an incident ~4 MeV electron beam at low incident dose rates of 0.01 rad/sec to 10 rad/sec. The steady-state RIC was found to agree well with the standard power law relation, σRIC(D) = kRIC(T) DÄ(T) between conductivity, óRIC and adsorbed dose rate, D. Both the proportionality constant, kRIC, and the power, Ä, were found to be temperature-dependent above ~250 K, with behavior consistent with photoconductivity models developed for localized trap states in disordered semiconductors. Below ~250 K, kRIC and Ä exhibited little change in any of the materials.
Gillespie, Jodie Corbridge, "Measurement of The Temperature Dependence of Radiation Induced Conductivity in Polymeric Dielectrics" (2013). All Graduate Theses and Dissertations. Paper 1953.
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