Date of Award:
Master of Science (MS)
Chemistry and Biochemistry
Lisa M. Berreau
John L. Hubbard
Robert S. Brown
Metal-organic frameworks are a new class of crystalline, porous solid-state materials with metal ions periodically linked by organic linkers. This gives rise to one-, two- or three-dimensional structures. Here, we compare the stability of similar metal sites toward external ligand (solvent) induced disruption of the coordination environment in metal complexes and in metal-organic frameworks. Our experimental results show that a metal site as node of a metal-organic framework retains much higher stability compared to a similar metal site in a metal complex.
Das, Sanjit, "Enhanced Structural Support of Metal Sites as Nodes in Metal-Organic Frameworks Compared to Metal Complexes" (2013). All Graduate Theses and Dissertations. 1736.
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