Fourier Transform-Infrared Studies of Thin H2SO4/H2O Films:Formation, Water Uptake, and Solid-Liquid Phase Changes

Document Type

Article

Journal/Book Title/Conference

Journal of Geophysical Research:Atmospheres

Volume

98

Issue

11

Publisher

American Geophysical Union

Publication Date

1993

First Page

20473

Last Page

20481

Abstract

Fourier transform‐infrared (FTIR) spectroscopy was used to examine films representative of stratospheric sulfuric acid aerosols. Thin films of sulfuric acid were formed in situ by the condensed phase reaction of SO3 with H2O. FTIR spectra show that the sulfuric acid films absorb water while cooling in the presence of water vapor. Using stratospheric water pressures, the most dilute solutions observed were >40 wt % before simultaneous ice formation and sulfuric acid freezing occurred. FTIR spectra also revealed that the sulfuric acid films crystallized mainly as sulfuric acid tetrahydrate (SAT). Crystallization occurred either when the composition was about 60 wt % H2SO4 or after ice formed on the films at temperatures 1–4 K below the ice frost point. Finally, we determined that the melting point for SAT depended on the background water pressure and was 216–219 K in the presence of 4 × 10−4 Torr H2O. Our results suggest that once frozen, sulfuric acid aerosols in the stratosphere are likely to melt at these temperatures, 30 K colder than previously thought.

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