Title

Energetics of proton transfer between carbon atoms (H3CH [BOND] CH3)−

Document Type

Article

Journal/Book Title

International Journal of Quantum Chemistry

Publication Date

1986

Publisher

Wiley

Volume

29

Issue

2

First Page

285

Last Page

292

DOI

10.1002/qua.560290218

Abstract

Ab initio calculations were carried out to study the potential energy surface of (H3CHCH3). The 6–31G* basis set is supplemented by a set of diffuse p functions on both C and H (with a range of exponents for the latter). The binding energy of CH4 and CH3 to form the (H3CHCH3) complex is about 2 kcal/mol, much smaller than for comparable ionic H-bonded systems involving O or N atoms. Nearly half of this interaction energy is due to correlation effects, computed at second and third orders of Møller-Plesset perturbation theory. Correlation is also responsible for substantial reductions in the energy barrier to proton transfer within the complex. This barrier is computed to be 13‒15 kcal/mol at the MP3 level, depending upon the exponent used for the H p functions.

Comments

Originally published by Wiley-Blackwell in the International Journal of Quantum Chemistry.

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