All Physics Faculty Publications

High-Resolution Spectra of Atmospheric Water Vaporin the Near-IR using a Raman-Shifted Alexandrite Laser

Document Type

Contribution to Book

Journal/Book Title/Conference

Lidar Remote Sensing for Industry and Environment Monitoring II

Volume

4484

Publication Date

2002

First Page

103

Last Page

111

Abstract

We have developed a pulsed, narrow line Raman shifted alexandrite laser to produce tunable near-IR radiation in the 1140 nm absorption band of water vapor. With the first Stokes Raman conversion in hydrogen, the full tuning range of alexandrite, 730-790 nm, can potentially cover the wavelength range 1050 1200 nm. The application to differential absorption lidar, DIAL, is the vertical profiling of humidity and temperature in the atmosphere. This paper reports the application of Raman-shifted alexandrite radiation for new quantitative measurements of the strengths and widths of water vapor absorption lines between 8865 and 8915 cm-1. Alexandrite wavelength determination was obtained with oxygen A-band rotational lines near 765 nm. Similar applications and studies of the water vapor band near 940 nm can be readily carried out by Raman-shifting in deuterium.

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