Insecticidal Cyclodepsipeptides From Metarhizium Anisopliae

Document Type

Article

Journal/Book Title/Conference

Journal of the Chemical Society, Perkin Transactions 1

Issue

12

Publication Date

1-1-1989

First Page

2347

Last Page

2357

Abstract

Bioassay-guided fractionation of the culture broth of Metarhizium anisopliae resulted in the isolation of 10 insecticidal cyclodepsipeptides–the destruxins, including two new compounds, destruxin E2 and chlorohydrin. Complete 1H and 13C n.m.r. assignments for the major destruxins, A and B, by various 1 D and 2D n.m.r. techniques provided a basis for identification and spectral assignments of other destruxins.

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