A Statistical Interpretation of the Rotational Temperature of NO Desorbed for Ru(001)

Document Type

Article

Journal/Book Title

Journal of Chemical Physics

Publication Date

1983

Volume

78

First Page

600

Abstract

A simple model of the rotational state of NO prior to thermal desorption from Ru(001) surface is developed in terms of the rotational heat capacity. The predicted rotational temperature of the desorbed species is consistent with known data on this system. The model is extended to predict translational energy anisotropy in the desorbed NO.

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