Document Type
Article
Journal/Book Title
ChemPhysChem
Publication Date
4-25-2018
Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
Volume
19
Issue
12
First Page
1
Last Page
9
Abstract
HOX (X=Cl, Br, I, and At) can engage in either a H‐bond (HB) or halogen bond (XB) with a base‐like HCN, NH3, and imidazole. Although the former is energetically preferred for X=Cl and Br, it is the XB that is more stable for At, with I showing little preference. MgY2 forms a Mg‐bond with the O atom of HOX, which grows stronger in the order X=Cl
Recommended Citation
Hui‐Li, X., Li Qing‐Zhong, Scheiner, S. I. (2018). Effect of Magnesium Bond on the Competition Between Hydrogen and Halogen Bonds and the Induction of Proton and Halogen Transfer. ChemPhysChem, 19(12), 1456-1464. https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201800102
Comments
This is the peer reviewed version of the following article: Hui‐Li, X., Li Qing‐Zhong, Scheiner, S. I. (2018). Effect of Magnesium Bond on the Competition Between Hydrogen and Halogen Bonds and the Induction of Proton and Halogen Transfer. ChemPhysChem, 19(12), 1456-1464. https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201800102, which has been published in final form at https://doi.org/10.1002/cphc.201800102. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.