Synthesis and Chemistry of Acyltriazolinedione Ylides and RelatedIntermediates: New Methods for the Preparation of Di- and Tricarbonyl Compounds
Document Type
Article
Journal/Book Title
Journal of Organic Chemistry
Publication Date
1990
Volume
55
First Page
197
Last Page
202
Abstract
��-Urazolylcarbonyl compounds can be easily oxidized to the corresponding ylides, and these ylides hydrolyzed to the corresponding carbonyl compounds. In addition these same urazole precursors can be converted to carbonyl compounds via a novel version of the Swern oxidation. These two methods not only are of synthetic value in the preparation of 1,2-dicarbonyl and 1,2,3-tricarbonyl compounds but also serve as useful probes for the formation of triazolinedione ylides and the related urazolium species.
Recommended Citation
R. M. Wilson, A. C. Hengge. “Synthesis and Chemistry of Acyltriazolinedione Ylides and Related Intermediates: New Methods for the Preparation of Di- and Tricarbonyl Compounds.” J. Org. Chem., 1990, 55, 197-202.
