Comparison of Lichen, Conifer Needles, Passive Air Sampling Devices, and Snowpack as Passive Sampling Media to Measure Semi-Volatile Organic Compounds in Remote Atmospheres.

Document Type

Article

Journal/Book Title

Environmental Science and Technology

Publication Date

11-16-2011

Publisher

American Chemical Society

Volume

45

Issue

24

First Page

10354

Last Page

10361

Abstract

A wide range of semivolatile organic compounds (SOCs), including pesticides and polycyclic aromatic hydrocarbons (PAHs), were measured in lichen, conifer needles, snowpack and XAD-based passive air sampling devices (PASDs) collected from 19 different U.S. national parks in order to compare the magnitude and mechanism of SOC accumulation in the different passive sampling media. Lichen accumulated the highest SOC concentrations, in part because of its long (and unknown) exposure period, whereas PASDs accumulated the lowest concentrations. However, only the PASD SOC concentrations can be used to calculate an average atmospheric gas-phase SOC concentration because the sampling rates are known and the media is uniform. Only the lichen and snowpack SOC accumulation profiles were statistically significantly correlated (r = 0.552, p-value 10 relative to needles and showed a greater accumulation of particle-phase PAHs.

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