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2004

A Mechanistic Study of the Alkaline Hydrolysis of Diaryl Sulfate Diesters, J. M. Younker and Alvan C. Hengge

2003

Steady‐State Absorption Rate Models for Use in Relaxation Rate Studies with Continuous Laser Excited Photothermal Lens Spectrometry, Stephen E. Bialkowski

Comparisons of Phosphorothioate with Phosphate Transfer Reactions for a Monoester, Diester and Triester: Isotope Effect Studies, I. E. Catrina and Alvan C. Hengge

Low Frequency Impedance Behavior of Montmorillonite Suspensions: Polarization Mechanisms in the Low Frequency Domain, Lynn M. Dudley, Stephen E. Bialkowski, Dani Or, and Chad Junkermeier

Transition State Differences in Hydrolysis Reactions of Alkyl versus Aryl Phosphate Monoester Monoanions, P. K. Grzyska, P. G. Czyryca, J. Purcell, and Alvan C. Hengge

Kinases, Alvan C. Hengge

Phosphatases, Alvan C. Hengge

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Rules for BN-Substitution in BCN-Fullerenes. Separation of BN and C Domains, Tapas Kar, Jayasree Pattanayak, and Steve Scheiner

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Comparison between hydrogen and dihydrogen bonds among H3BNH3, H2BNH2, and NH3, T. Kar and Steve Scheiner

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A DFT/TDDFT Study of Group 4A Metal Porphyrins, Meng-Sheng Liao and Steve Scheiner

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DFT Calculations and Spectral Measurements of Charge-Transfer Complexes Formed by Aromatic Amines and Nitrogen Heterocycles with Tetracyanoethylene and Chloranil, M.-S. Liao, Y. Lu, V. D. Parker, and Steve Scheiner

Performance Assessment of Density-Functional Methods for Study of Charge-Transfer Complexes, M.-S. Liao, Y. Lu, and Steve Scheiner

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Comparison of BN and AlN Substitution on the Structure and Properties of C60 Fullerene, J. Pattanayak, T. Kar, and Steve Scheiner

A Comparison of Phosphonothioic Acids with Phosphonic Acids as Phosphatase Inhibitors, K. Swierczek, A. S. Pandey, J. Peters, and Alvan C. Hengge

A convenient synthesis of phosphonothioic acids, K. Swierczek, J. Peters, and Alvan C. Hengge

2002

Using an Expectation‐Maximization Algorithm to Obtain Dielectric Relaxation Time Spectra of Aqueous Montmorillonite Clay Suspensions, Stephen E. Bialkowski, Lynn Dudley, and Dani Or

Isotope effects on enzymatic and nonenzymatic reactions of phosphorothioates, I. E. Catrina, P. G. Czyryca, and Alvan C. Hengge

Photothermal Spectrometry in Small Liquid Channels, Agnes B. Chartier and Stephen E. Bialkowski

Generality of Solvation Effects on the Hydrolysis Rates of Phosphate Monoesters, and Their Possible Relevance to Enzymatic Catalysis, P. K. Grzyska, P. G. Czyryca, J. Golightly, K. Small, P. Larsen, R. H. Hoff, and Alvan C. Hengge

Isotope Effects In the Study of Phosphoryl and Sulfuryl Transfer Reactions, Alvan C. Hengge

An Altered Mechanism of Hydrolysis for a Metal-Complexed Phosphate Diester, T. Humphry, M. Forconi, N. H. Williams, and Alvan C. Hengge

A Comparative Study of Metal-Porphyrins, -Porphyrazines, and -Phthalocyanines, M.-S. Liao and Steve Scheiner

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Electronic structure and bonding in metal porphyrins, metal=Fe, Co, Ni, Cu, Zn, M.-S. Liao and Steve Scheiner

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Electronic structure and bonding in unligated and ligated FeII porphyrins, M.-S. Liao and Steve Scheiner

Relativistic Effects in Iron-, Ruthenium-, and Osmium Porphyrins, M.-S. Liao and Steve Scheiner

The catalytic mechanism of Cdc25A phosphatase, D. F. McCain, I. E. Catrina, Alvan C. Hengge, and Z. Y. Zhang

Boron-Nitrogen (BN) Substitution of Fullerenes: C60 to C12B24N24 CBN Ball, J. Pattanayak, T. Kar, and Steve Scheiner

Metal ion catalyzed hydrolysis of ethyl pnitrophenyl phosphate, J. Rawlings, W. W. Cleland, and Alvan C. Hengge

Acetylene as Potential Hydrogen-Bond Proton Acceptor, Steve Scheiner and S. J. Grabowski

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Red- versus Blue-Shifting Hydrogen Bonds: Are There Fundamental Distinctions?, Steve Scheiner and T. Kar

Substituent Effects upon Protonation-Induced Red Shift of Phenyl-Pyridine Copolymers, Steve Scheiner and T. Kar

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Substituent Effects upon Protonation-Induced Red Shift of Phenyl−Pyridine Copolymers, Steve Scheiner and T. Kar

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Comparison of Various Types of Hydrogen Bonds Involving Aromatic Amino Acids, Steve Scheiner, Tapas Kar, and Jayasree Pattanayak

Electronic Structure and Bonding in Metal Porphyrins and Phthalocyanines, Steve Scheiner and M.-S. Liao

2001

Modeling Maxwell‐Wagner and diffuse double layer polarization in low frequency impedance spectra of clay suspensions, Stephen E. Bialkowski, Lynn M. Dudley, and Dani Or

Using expectation maximization to obtain dielectric relaxation time spectra of aqueous montmorillonite clay suspensions, Stephen E. Bialkowski, Lynn M. Dudley, and Dani Or

Optical Bleaching in Continuous Laser Excited Photothermal Lens Spectrometry, Agnes Chartier and Stephen E. Bialkowski

The mechanism of the phosphoryl transfer catalyzed by Yersinia protein-tyrosine phosphatase: a computational and isotope effect study, P. G. Czyryca and Alvan C. Hengge

Isotope effects in the study of enzymatic phosphoryl transfer reactions, Alvan C. Hengge

Role of Protein Conformational Mobility in Enzyme Catalysis - Acylation of α-Chymotrypsin by Specific Peptide Substrates, Alvan C. Hengge and Ross L. Stein

Isotope Effects and Medium Effects on Sulfuryl Transfer Reactions, R. H. Hoff, P. Larsen, and Alvan C. Hengge

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Proton Conduction by a Chain of Water Molecules in Carbonic Anhydrase, A. Isaev and Steve Scheiner

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Insertion of Lithium Ions into Carbon Nanotubes: An ab Initio Study, T. Kar, J. Pattanayak, and Steve Scheiner

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Electronic structure and bonding in metal phthalocyanines, Metal=Fe, Co, Ni, Cu, Zn, Mg, M.-S. Liao and Steve Scheiner

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Boron−Nitrogen (BN) Substitution Patterns in C/BN Hybrid Fullerenes: C60-2x(BN)x (x = 1−7), J. Pattanayak, T. Kar, and Steve Scheiner

Transition state analysis and requirement of Asp-262 general acid/base catalyst for full activation of dual-specificity phosphatase MKP3 by extracellular regulated kinase, J. D. Rigas, R. H. Hoff, A. E. Rice, Alvan C. Hengge, and J. M. Denu

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Influence of Hybridization and Substitution upon the Properties of the CH··O Hydrogen Bond, Steve Scheiner, S. J. Grabowski, and T. Kar

Strength of the C-H···O Hydrogen Bond of Amino Acid Residues, Steve Scheiner, T. Kar, and Y. Gu

Comparison of Detection Limits and Relative Responses for Alternative Fluorocarbons by GC‐ECD, GCAED, and GC‐MS, Sonia R. Sousa and Stephen E. Bialkowski

Analytic function fit of potential energy of proton transfer in N2H7+, Rong-Shun Wang, Xiu-Mei Pan, Zhong-Min Su, and Steve Scheiner

2000

Comparison of the CH...N and CH...O Interactions Involving Substituted Alkanes, Y. Gu, T. Kar, and Steve Scheiner

Kinetic isotope effects and stereochemical studies on a ribonuclease model: Hydrolysis reactions of uridine 3 '-pnitrophenyl phosphate, Alvan C. Hengge, K. S. Bruzik, A. E. Tobin, W. W. Cleland, and M. D. Tsai

Effects on General Acid Catalysis from Mutations of the Invariant Tryptophan and Arginine Residues in the Protein Tyrosine Phosphatase from Yersinia, R. H. Hoff, Alvan C. Hengge, L. Wu, Y. F. Keng, and Z. Y. Zhang

Mutation of Arg-166 of Alkaline Phosphatase Alters the Thio Effect but Not the Transition State for Phosphoryl Transfer. Implications for the Interpretation of Thio Effects in Reactions of Phosphatases, K. M. Holtz, I. E. Catrina, Alvan C. Hengge, and E. R. Kantrowitz

Structure, Stability and Bonding of (BC2N)n, n=2,3: An Ab Initio Study, T. Kar, M. Cuma, and Steve Scheiner

Thermal Lens Calorimetry: A Novel Approach to the Study of Thermodynamics, George R. Long and Stephen E. Bialkowski

Fractured Zone Plates for Spatial Separation of Frequencies, Richard D. Rallison and Stephen E. Bialkowski

Lanthanide Catalyzed Cyclization of Uridine 3'-p-Nitrophenyl Phosphate, M. A. Rishavy, Alvan C. Hengge, and W. W. Cleland

Calculation of Isotope Effects from First Principles, Steve Scheiner

CH···O Hydrogen Bonding, Steve Scheiner

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Theoretical Studies of Excited State Proton Transfer in Small Model Systems, Steve Scheiner

Evaluation of the H-Bonding Properties of CH...O Interactions Based upon NMR Spectra, Steve Scheiner, Y. Gu, and T. Kar

1999

Using an Optical Novelty Filter to Enhance Contrast in Photothermal Refraction Spectrometry, Stephen E. Bialkowski

Methods for Modeling and Diagnosis of Nonlinear Absorption in Photothermal and Photoacoustic Spectrometry of Homogeneous Fluids, Stephen E. Bialkowski and Agnes Chartier

Using Slow Measurement Systems to Measure Fast Excited‐State Kinetics with Nonlinear Rate‐ Competitive Optical Bleaching, Stephen E. Bialkowski and Agnes Chartier

Using Sub‐Microliter Cylindrical Sample Cells for Photothermal Lens Spectrometry of Stable and Photo‐Labile Species, Stephen E. Bialkowski and Agnes Chartier

Comparisons of Phosphorothioate and Phosphate Monoester Transfer Reactions: Activation Parameters, Solvent Effects, and the Effect of Metal Ions, I. E. Catrina and Alvan C. Hengge

Effect of Adjoining Aromatic Ring upon Excited State Proton Transfer. o-Hydroxybenzaldehyde, M. Cuma, Steve Scheiner, and T. Kar

Low frequency behavior of colloidal suspensions. Modeling Maxwell‐Wagner and diffuse double layer polarization in low frequency impedance spectra of clay suspensions, Lynn M. Dudley, Dani Or, Stephen E. Bialkowski, and Chad Junkermeier

Effects of Chemical Substitution upon Excited State Proton Transfer. Fluoroderivatives of Salicylaldimine, M. Forés and Steve Scheiner

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Fundamental Properties of the CH...O Interaction: Is It a True Hydrogen Bond?, Yanliang Gu, Tapas Kar, and Steve Scheiner

Insights from Heavy-Atom Isotope Effects on Phosphoryl and Thiophosphoryl Transfer Reactions, Alvan C. Hengge

The Transition State of the Phosphoryl Transfer Reaction Catalyzed by the Lambda Ser/Thr Protein Phosphatase, R. H. Hoff, P. Mertz, F. Rusnak, and Alvan C. Hengge

Does Positive Charge at the Active Sites of Phosphatases Cause a Change in Mechanism? The Effect of the Conserved Arginine on the Transition State for Phosphoryl Transfer In the Protein-tyrosine Phosphatase from Yersinia, R. H. Hoff, L. Wu, B. Zhou, Z. Y. Zhang, and Alvan C. Hengge

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Comparison of methods for calculating the properties of intramolecular hydrogen bonds. Excited state proton transfer, T. Kar, Steve Scheiner, and M. Cuma

Does Thermochemical Mimicry Extend to Gibbs Energies? The Differences of K+ and NH4+, and of Na+ and H3O+, J. F. Liebman and Steve Scheiner

Comparison of the Reaction Progress of Calcineurin with Mn2+ and Mg2+, B. L. Martin, L. A. Jurado, and Alvan C. Hengge

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Ionic Hydrogen Bond Effects on the Acidities, Basicities, Solvation, Solvent Bridging, and Self-Assembly of Carboxylic Groups, Michael Meot-Ner, Donald E. Elmore, and Steve Scheiner

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Activation and Cleavage of H-R Bonds through Intermolecular H...H Bonding upon Reaction of Proton Donors HR with 18-Electron Transition Metal Hydrides, G. Orlova, Steve Scheiner, and T. Kar

Fundamental Features of Hydrogen Bonds, Steve Scheiner

Proton Transfers in Biological Systems, Steve Scheiner

1998

Laser‐Excited Photothermal Lens Spectrometry in a Low‐Volume Cylindrical Sample Cell, Stephen E. Bialkowski

Overcoming the Multiplex‐Disadvantage using Maximum‐Likelihood Inversion, Stephen E. Bialkowski

Progress Toward a Better Understanding of Signal Generation Processes in the Laser‐Excited Photothermal Spectroscopy of Homogeneous Samples, Stephen E. Bialkowski

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Competition between Rotamerization and Proton Transfer in o-Hydroxybenzaldehyde, Martin Cuma, Steve Scheiner, and Tapas Kar

Effect of Nonproximate Atomic Substitution on Excited State Intramolecular Proton Transfer, M. Cuma, C. Thompson, and Steve Scheiner

Transfer of the PO32- Group, Alvan C. Hengge

Isotope Effects on Enzyme-Catalyzed Acyl Transfer from p-Nitrophenyl Acetate: Concerted Mechanisms and Increased Hyperconjugation in the Transition State, R. A. Hess, Alvan C. Hengge, and W. W. Cleland

A Facile High-Yield Synthesis and Purification of Tetrabutylammonium Tetrabutylborate, R. H. Hoff and Alvan C. Hengge

Entropy and Enthalpy Contributions to Solvent Effects on Phosphate Monoester Solvolysis. The Importance of Entropy Effects in the Dissociative Transition State, R. H. Hoff and Alvan C. Hengge

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Structure, Stability, and Bonding of BC2N: An Ab Initio Study, T. Kar, M. Cuma, and Steve Scheiner

Ab Initio Calculations of Hardness and Chemical Potential of Open Shell Systems Using SCF, MP2, and MP4 Methods, T. Kar, Steve Scheiner, and A. B. Sannigrahi

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Hardness and Chemical Potential Profiles for Some Open Shell HAB → HBA Type Reactions. Ab Initio and Density Functional Study, T. Kar, Steve Scheiner, and A. B. Sannigrahi

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Ionic Hydrogen Bonds in Bioenergetics. 3. Proton Transport in Membranes, Modeled by Ketone/Water Clusters, Michael Meot-Ner, Steve Scheiner, and Wa On Yu

Inter- and Intramolecular Hydrogen Bonds with Transition Metal Atoms in Metallocenes of the Iron Subgroup, G. Orlova and Steve Scheiner

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Intermolecular H...H Bonding and Proton Transfer in Semisandwich Re and Ru Complexes, G. Orlova and Steve Scheiner

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Intermolecular MH...HF Bonding in Monohydride Mo and W Complexes, G. Orlova and Steve Scheiner

1997

Diffraction Effects in Single‐ and Two‐Laser Photothermal Lens Spectroscopy, Stephen E. Bialkowski and Agnes Chartier

Molecular Interactions at Octadecylated Chromatographic Surfaces, James W. Burns, Stephen E. Bialkowski, and David B. Marshall

Photothermal Lens Spectrometry of Homogeneous Fluids with Incoherent White‐Light Excitation Using a Cylindrical Sample Cell, Agnes Chartier and Stephen E. Bialkowski